吐松
教授 硕士生导师
办公室:化学楼594
电话:0592-2186020,13055222894
Email:tusong@xmu.edu.cn
个人简历
学士(精细化工专业,大连理工大学,2001)
博士(应用化学专业,大连理工大学,硕博连读,2006)
博士后(日本冈山大学,2008-2009)
访问学者(日本东京大学,2018-2019)
2006年12月至今在厦门大学任教,2010年晋升为副教授,2016年晋升为教授。2013年入选福建省高等学校新世纪优秀人才支持计划,2019年入选厦门市第十二批“双百计划”领军型创业人才(A类)。
研究方向
精细化工及环境友好精细有机合成(精细化学品合成新技术、新方法,绿色化学合成);有机光电功能材料的制备与研究;手性过渡金属催化剂的开发及应用。
教学工作
曾讲授本科生课程《精细化工》、《制药化工原理》、《化学工程基础》、《化工基础实验》,研究生课程《精细化学工程导论》;现讲授本科生课程《化工环保与安全》、《化工专业实验》;指导本科生专业实习及毕业设计。
承担的课题:
1. 精细化工方面:苯并五元环取代肟醚类strobilurin化合物的设计、合成和生物活性研究(国家自然科学基金,主持);乙氧基喹啉高效清洁生产工艺开发与优化(广西科学研究与技术开发计划项目,主持);γ-烷基-丁内酯类香料合成工艺开发(厦门市科技计划项目,主持);企业委托(合作)课题多项(医药、香料等精细化学品生产工艺开发,主持)
2. 功能材料方面:大功率LED用石墨烯散热产品产业化技术研发(福建省发改委产业技术研究开发项目,子课题负责人);导热功能高分子复合材料研发(厦门市科技计划项目,主持);超级电容器用芴类寡聚物电活性材料的制备与性能研究(厦门大学基础创新科研基金,主持);企业委托(合作)课题1项(主持)
3. 生物质基精细化学品开发方面:利用蟹虾壳等水/海产品加工业废弃物制备壳聚糖新工艺开发(福建省科技计划重点项目,主持);微藻催化液化制备高性能生物燃油关键技术开发(厦门大学校长基金项目,主持)
近期主要代表论著:
1. Yuanqiong Lin, Xiao Zhang, Jinchuan Lu, Xiaohan Lin, Yinghua Lu, Xin Li*, Song Tu*. Improvement in dibenzofuran-based hole transport materials for flexible perovskite solar cells. Molecules, 2024, 29 (6), 1208.
2. Shaoping Qian, Yingqi Kong, Hongcai Cheng, Song Tu*, Chunyang Zhai*. Interfacial interaction improvement of polylactic acid/bamboo-char biocomposites for high toughness, good strength, and excellent thermal stability. Surfaces and Interfaces,2023, 42, 103315.
3. Jun Fang, Yixian Zhu, Xihuang Zeng, Xiaohan Lin, Bin Deng, Yinghua Lu, Song Tu*. Synthesis and fungicidal activities of benzofuran-substitutes cinnamamide compounds. Chemistryselect,2023, 8 (31), e202302114.
4. Chen-Jie Li, Jie Zhang, Zi-Long Huang, Yu-Xing Gao, Li-Yi Ye, Ying-Wu Yin, Song Tu*. Synthesis and photovoltaic properties of simple fluorene-based triphenylamine metal-free organic sensitizers for dye-sensitized solar cells.Russian Journal of Organic Chemistry, 2023, 59(2), 312-323.
5. Xinwei Zhang, Jun Fang, Chenjie Li, Jie Zhang, Shuwen Yang, Bin Deng, Song Tu*.Design, Synthesis, and Fungicidal Activities of Indole-Modified Cinnamamide Derivatives, Chem. Biodiversity,2022, 19, e202200971.
6. Yingping Lai, Weitong Wang, Jiajia Zhao, Song Tu, Yingwu Yin, Liyi Ye*.Chitosan Na-montmorillonite films incorporated with citric acid for prolonging cherry tomatoes shelf life.Food Packaging and Shelf Life, 2022, 33, 100879.
7. Yingxiang Hua, Yanchao Lin, Wenyi Chen, Liyi Ye, Yingwu Yin, Yuxing Gao*, Song Tu*. Copper-catalyzed oxidative cross-dehydrogenative coupling (CDC) reaction of alcohols with secondary phosphine oxides, Tetrahedron Letters, 2022, 99, 153822.
8. YihuaRenDianzhengZhangYingwuYinZhangkunYeZhengqingYinSong TuLiyiYeXueyunChenShengyunZhaoMechanically strong, thermostable, and flame-retardant composites enabled by Brown paper made from bamboo.Composites Science and Technology, 2022, 226, 109544.
9. WeitongWang, RuiKang,YingwuYin,Song Tu, Liyi Ye*. Two-step pyrolysis biochar derived from agro-waste for antibiotics removal: Mechanisms and stability. 2022,Chemosphere, 292, 133454.
10. Baffa Haruna, Weitu Hong, Warsame Ibrahim Mohamed, Jiami Guo, Liyi Ye, Yingwu Yin, Yuxing Gao*, Song Tu*. Visible-light-induced oxidative C–H functionalization of unreactive cycloalkanes, alcohols, and ethers with alkynylphosphine oxides into benzo[b]phosphole oxides under photocatalyst-, metal-, and base-free conditions. J. Org. Chem., 2021,86 (18), 13092-13099.
11. Weitu Hong, Junhong Chen, Qiuyu Ding, Yuxing Gao, Liyi Ye*, Yingwu Yin, Song Tu*. Efficient thermochemical liquefaction of microalgae Haematococcus pluvialis for production of high quality biocrude with high selectivity over Fe/montmorillonite catalyst. Journal of the Energy Institute,2021, 97, 73-79.
12. Dumei Ma, Shanshan Hu, Sirui Chen, Jiaoting Pan, Song Tu, Yingwu Yin,* Yuxing Gao,* Yufen Zhao. Palladium-catalyzed addition/cyclization of (2-hydroxyaryl)boronic acids with alkynylphosphonates: Access to phosphacoumarins. Org. Lett. 2020, 22(20), 8156-8160.
13. Bangxian Peng, Rusen Zhou, Ying Chen, Song Tu, Yingwu Yin, Liyi Ye. Immobilization of nano-zero-valent irons by carboxylated cellulose nanocrystals for wastewater remediation. Front. Chem. Sci. Eng. 2020, 14(6): 1006-1017.
14. Jiami Guo, Chenlu Mao, Bin Deng, Liyi Ye, Yingwu Yin, Yuxing Gao*, Song Tu*. Azobisisobutyronitrile-initiated oxidative C-H functionalization of simple alcohols with diaryl(arylethynyl)phosphine oxides: A metal-free approach toward hydroxymethyl benzo[b]phosphole oxides and 6H‑indeno[2,1‑b]phosphindole 5‑oxide derivatives. J. Org. Chem., 2020, 85, 6359-6371.
15. Yaqiang Xie, Ju Lin, Hongying Lin, Yue Jiang, Jun Liang, Hongtao Wang, Song Tu*, Jun Li*. Removal of anionic hexavalent chromium and methyl orange pollutants by using imidazolium-based mesoporous poly(ionic liquid)s as efficient adsorbents in column. Journal of Hazardous Materials, 2020, 392, 122496.
16. Wei Guo, Yingwu Yin*, Na Pi, Feng Liu, Song Tu, Liyi Ye. Investigation on a novel mixed dialkyl oxalate system as an oxygenated fuel additive. Engry & Fuels, 2020, 34 (4), 4213-4220.
17. Yaqiang Xie, Ju Lin, Jun Liang, Minghong Li, Yawen Fu, Hongtao Wang, Song Tu*, Jun Li*. Hypercrosslinked mesoporous poly(ionic liquid)s with high density of ion pairs: Efficient adsorbents for Cr(VI) removal via ion-exchange. Chemical Engineering Journal, 2019, 378, 122107.
18. Lei Zhou, Rusen Zhou, Jingshuai Zuo, Song Tu, Yingwu Yin, Liyi Ye*. Unsaturated polyester resins with low- viscosity: preparation and mechanical properties enhancement by isophorone diisocyanate (IPDI) modification. Materials Research Express, 2019, 6 (11), 115305.
19. Yaqiang Xie, Jun Liang, Yawen Fu, Ju Lin, Hongtao Wang, Song Tu*, Jun Li*.Poly(ionic liquid)s with high density of nucleophile /electrophile for CO2fixation to cyclic carbonates at mild conditions. Journal of CO₂ Utilization, 2019, 32, 281-289.
20. Yaqiang Xie, Jun Liang, Yawen Fu, Mengting Huang, Hongtao Wang, Song Tu*, Jun Li*. Hypercrosslinked mesoporous poly (ionic liquid)s with high ionic density for efficient CO2 capture and conversion into cyclic carbonate.Journal of Materials Chemistry A, 2018, 6 (15), 6660-6666.
21. Yaqiang Xie, Qing Sun, Yawen Fu, Lei Song, Jun Liang, Xun Xu, Hongtao Wang, Jianhui Li, Song Tu*, Xin Lu*, Jun Li*. Sponge-like quaternary ammonium-based poly (ionic liquid)s: toward high CO2 capture and efficient cycloaddition at mild conditions.Journal of Materials Chemistry A, 2017, 5 (48), 25594-25600.
22. Ling-Zhu Feng, Xue-Feng Shi, Jing Xie, Da-Ming Zheng, Hui-Hui Niu, Yi-Bing Huang, Li-Yi Ye, Ying-Wu Yin, Song Tu*. Synthesis, characterization, and electroluminescent properties of monodisperse oligofluorenes as emissive materials for organic electroluminescent devices. Journal of the Taiwan Institute of Chemical Engineers. 2017, 71, 69-76.
23. Rusen Zhou, Renwu Zhou, Xianhui Zhang, Song Tu, Yingwu Yin, Size Yang, Liyi Ye∗. An efficient bio-adsorbent for the removal of dye: Adsorption studies and cold atmospheric plasma regeneration. Journal of the Taiwan Institute of Chemical Engineers,2016,68, 372-378.
24. Jiuxing Li, Zhi Zhu, Fang Liu, Bingqing Zhu, Yanli Ma, Jinmao Yan, Bingqian Lin, Guoliang Ke, Rudi Liu, Leiji Zhou, Song Tu, Chaoyong Yang∗.DNA-mediated morphological control of silver nanoparticles. Small, 2016, 12 (39), 5449-5457.
25. Rusen Zhou, Renwu Zhou, Shuai Wang, Zhou Lan, Xianhui Zhang, Yingwu Yin, Song Tu, Size Yang, Liyi Ye∗. Fast liquefaction of bamboo shoot shell with liquid-phase microplasma assisted technolog. Bioresource Technology. 2016, 218, 1275-1278.
26. Jiuxing Li, Zhi Zhu, Bingqing Zhu, Yanli Ma, Bingqian Lin, Rudi Liu, Yanling Song, Hui Lin, Song Tu, Chaoyong Yang∗. Surface-enhanced raman scattering active plasmonic nanoparticles with ultrasmall interior nanogap for multiplex quantitative detection and cancer cell imaging. Analytical Chemistry, 2016, 88 (15), 7828-7836.
27. Huidong Yan, Liufang Zeng, Yaqiang Xie, Yu Cui, Liyi Ye, Song Tu*. N-Methylation of poor nucleophilic aromatic amines with dimethyl carbonate. Research on Chemical Intermediates. 2016, 40 (6), 5951-5960.
28. Zhiming Luo, Jingmiao Zhang, Canfeng Zhuang, Song Tu, Yingwu Yin, Liyi Ye∗. An eco-friendly composite adsorbent for efficient removal of Cu2+from aqueous solution. Journal of the Taiwan Institute of Chemical Engineers. 2016,60, 479-487.
29. Yi-Bing Huang, Yu Cui, Liu-Fang Zeng, You-Yu Shen, Ling-Zhu Feng, Xue-Feng Shi, Li-Yi Ye, Ying-Wu Yin, Song Tu*. Synthesis, optical, and electrochemical properties of 4-fluorophenyl end-capped oligofluorenes. Journal of Fluorine Chemistry. 2015, 178,195-201.
30. Jiuxing Li, Bingqing Zhu, ZhiZhu, Yicong Zhang, Xiujie Yao, Song Tu*, Rudi Liu, ShashaJia, Chaoyong James Yang*. Simple and rapid functionalization of gold nanorods with oligonucleotides using an mPEG-SH/Tween 20-assisted approach. Langmuir, 2015, 31(28), 7869-7876.
31. Liyi Ye*, Jingmiao Zhang, Jie Zhao, Zhiming Luo, Song Tu*, Yingwu Yin. Properties of biochar obtained from pyrolysis of bamboo shoot shell.Journal of Analytical and Applied Pyrolysis, 2015, 114,172-178.
32. Ya-Qiang Xie, Zi-Long Huang, Hui-Dong Yan, Jun Li, Li-Yi Ye, Li-Ming Che, Song Tu*. Design, Synthesis, and biological activity of oxime ether strobilurin derivatives containing indole moiety as novel fungicide. Chemical Biology & Drug Design. 2015, 85 (6), 743-755.
33. Liyi Ye, Jianshe Liu, Chen Zhang, Yaqiang Xie, Song Tu*. A novel and efficient method for purification of tert-butylhydroquinone. Separation Science and Technology,2015, 50 (6), 820-823.
34. Ya-Qiang Xie, Yi-Bing Huang, Jian-She Liu, Li-Yi Ye, Li-Ming Che, Song Tu,* Chang-Ling Liu*. Design, synthesis and structure-activity relationship of novel oxime ether strobilurin derivatives containing substituted benzofurans. Pest Manag. Sci. 2015, 71 (3), 404-414.
35. Jiuxing Li, Binqing Zhu, Xiujie Yao, Yicong Zhang, Zhi Zhu, Song Tu, Shasha Jia, Rudi Liu, Huaizhi Kang,* and Chaoyong James Yang*. Synergetic approach for simple and rapid conjugation of gold nanoparticles with oligonucleotides. ACS Applied Materials & Interfaces, 2014, 6(19), 16800-16807.
36. Jianshe Liu, Yaqiang Xie, Liyi Ye, Huidong Yan, Song Tu*. Efficient and green preparation of 2-imidazolidinone using sulfamic acid as acidic catalyst. Organic Preparations and Procedures International, 2014, 46(5), 453-156.
37. Song Tu,* Ya-Qiang Xie, Si-Zhe Gui, Li-Yi Ye, Zi-Long Huang, Yi-Bing Huang, Li-Ming Che. Synthesis and fungicidal activities of novel benzothiophene-substituted oxime ether strobilurins. Bioorganic & Medicinal Chemistry Letters.2014,24, 2173-2176.
38. Song Tu*, Youyu Shen, Wan Dong, Jing Yang, Chen Zhang, Liyi Ye*. Efficient and convenient preparation of γ-nonalactone, with use of Dean-Stark trapto Remove Methanol. Research on Chemical Intermediates. 2014, 40, 1613-1618.
39. Liyi Ye,* Jingmiao Zhang, Jie Zhao, Song Tu*. Liquefaction of bamboo shoot shell for the production of polyols. Bioresource Technology, 2014, 153, 147-153.
40. Weng Huichao, Luo Jianjun, Yin Yingwu*, Duan Zhanting, Sha Yong, Ye Liyi, Tu Song, Lai Yonghua. Performance characteristics of a new spherical metal mesh packing. Chemical Engineering and Processing, 2013, 72, 68-73.
41. Song Tu,* Wan Dong, Jing Yang, Chen Zhang and Youyu Shen. Efficient preparation of racemic γ-nonalactone. Organic Preparations and Procedures International, 2013,45(1), 72-74.
42. Ya-Ping Zhu, Song Tu, Zheng-Hong Luo. Modeling for the catalytic coupling reaction of carbon monoxide to diethyl oxalate in fixed-bed reactors: Reactor model and its applications, Chemical Engineering Research & Design, 2012, 90(9), 1361-1371.
43. Sha Yong, Chen Hongling, Yin Yingwu, Tu Song, Ye Liyi, Zheng Yanmei. Characteristics of the Marangoni Convection Induced in Initial Quiescent Water. Industrial & Engineering Chemistry Research.2010, 49(18): 8770-8777.
44. Ye Jianchu, Tu Song, Sha Yong, Investigation to biodiesel production by the two-step homogeneous base-catalyzed transesterification. Bioresource Technology, 2010, 101(19),7368-7374.
45. Song Tu*, Yong Sha, Long-He Xu, Zong-Yuan Xiao, Li-Yi Ye and Jun Fang. Studies on the synthesis of 2-acyl-1H-indenes via one-pot palladium-catalysed tandem Heck–aldol reaction. Journal of Chemical Research, 2010, 34(5), 254-258.
46. Hankun Xu, Jun Fang, Mingli Guo, Xiaohuan Lu, Xiaolan Wei, Song Tu. Novel anion exchange membrane based on copolymer of methyl methacrylate, vinylbenzyl chloride and ethyl acrylate for alkaline fuel cells.Journal of Membrane Science, 2010, 354(1-2), 206-211
47. Yanying Zhang, Song Tu, Koichi Mitsudo, Hideo Tanaka, Shunzo Suematsu, Kenji Machida, Daisuke Horii, Shuichi Ishimoto, Kenji Tamamitsu. Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates. Tetrahedron Letters, 2009,50 (44), 6057-6059.
48. Song Tu*, Long-He Xu, Li-Yi Ye, Xi Wang, Yong Sha, Zong-Yuan Xiao. Synthesis and biological activities of novel indene substituted oxime ether strobilurins.J. Agric. Food Chem.2008,56 (13), 5247-5253.
49. Zongyuan Xiao, Wenjing Wang, Liyi Ye, Yong Sha, Song Tu. Effect of Cd2+ as a stabilizer in the electroless nickel plating system. Surface & Coatings Technology. 2008, 202, 5008-5011.
50. Song Tu, Long-He Xu, Chun-Rui Yu. Efficient one-pot synthesis of 2-carbonyl-1-indanols by palladium-catalyzed tandem Heck-aldol reaction. Synth. Commun. 2008, 38 (15), 2662-2671.
51. Song Tu, Long-He Xu, Chun-Rui Yu, Hong Zhang, Zhi-Nian Li. Synthesis and biological activities of novel oxime ethers. Chinese Journal of Organic Chemistry, 2007, 27 (2), 228-234.
52. Chun-Rui Yu,Long-He Xu,Song Tu,Zhi-Nian Li,Bin Li. Synthesis and bioactivity of novel (3-chloro-5-(trifluoromethyl)pyridin-2-yloxy)phenyl containing acrylate and acrylonitrile derivatives. Journal of Fluorine Chemistry, 2006, 127 (12), 1540-1546.
53. Jian-Xin Yang, Xin-Liang Wang, SongTu, Long-He Xu. Studies on the synthesis and spectral properties of novel 4-benzofuranyl-1,8-naphthalimide derivatives. Dyes Pigments,2005, 67 (1), 27-33.
授权专利:
1. 吐松,张杰,卢英华,沈亮,陈学云。一种4-硝基茴香硫醚的合成方法。专利号:ZL 202211391614.8,授权公告日:2024年6月11日。
2. 吐松,洪伟图,叶李艺,高玉兴,陈学云 ,尹应武。一种特丁基对苯二酚的合成方法。专利号ZL202011500661.2,授权公告日:2022年4月12日。
3. 吐松,傅江铭,张艳,林新萍,高玉兴,尹应武,叶李艺。一种石墨烯/聚苯醚合金导热复合材料的制备方法。专利号:ZL201911202655.6,授权公告日:2021年3月30日。
4. 吐松,郑达明,毛晨路,林新萍,叶李艺,陈学云,尹应武。一种1,3-二甲基-2-咪唑啉酮的合成方法。专利号:ZL201711293633.6,授权公告日:2020年10月2日。
5. 吐松,丁秋宇,高玉兴,林新萍,尹应武,叶李艺,陈学云。一种微藻催化液化制备生物油的方法。专利号:ZL201811073505.5,授权公告日:2020年4月10日。
6. 吐松,解菁,叶李艺,陈学云,尹应武。一种烷基糖苷的生产方法。专利号:ZL201710783558.5,授权公告日:2019年11月22日。
7. 吐松,刘建设,卢英华,肖宗源,蓝家勇,阮鹭韩。一种2-咪唑烷酮的合成方法,专利号:ZL201310483582.9,授权公告日:2015年1月21日。
8. 吐松,董万,方百发。一种合成γ-壬内酯的方法。专利号:ZL201210064415.6,授权公告日:2014年10月8日。
9. 吐松,张琛,方百发。一种叔丁基对苯二酚的提纯方法。专利号:ZL201210362783.9,授权公告日:2014年7月30日。
10. 吐松,徐龙鹤,张弘,李志念,于春睿,崔东亮。茚取代肟醚类杀菌、杀虫剂。专利号:ZL200610200228.0,授权公告日:2009年5月20日。